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Conference Papers | 2020

Dynamische Simulation von Absorptionskälteanlagen – Dymola-Modell einer H2O/LiBr-Absorptionskälteanlage

Wernhart M, Rieberer R, Zlabinger S, Unterberger V, Gölles M. Dynamische Simulation von Absorptionskälteanlagen: Dymola-Modell einer H2O/LiBr-Absorptionskälteanlage. in Proc. Deutsche Kälte-Klima-Tagung 2020. Deutscher Kälte- und Klimatechnischer Verein e.V. 2020

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Absorptionskälteanlagen können einen wesentlichen Beitrag zur Verringerung von CO2-Emissionen leisten, wenn Wärme aus regenerativen Energieträgern oder Abwärme aus industriellen Prozessen zum Antrieb verwendet wird. Absorptionskälteanlagen weisen bereits jetzt eine hohe Effizienz auf, bei veränderlichen Betriebsbedingungen kann diese je nach vorhandenen Stellgliedern weiter gesteigert werden. Dazu werden im Rahmen des Forschungsprojektes „Heat Pumping Systems Control (HPC)“ zwei Absorptionskälteanlagen – eine mit der Stoffpaarung Ammoniak/Wasser (NH3/H2O) und eine mit der Stoffpaarung Wasser/Lithiumbromid (H2O/LiBr) – untersucht, um für unterschiedliche Anwendungen optimale Betriebsstrategien zu entwickeln. Zur Berücksichtigung der Zustandsänderungen in der Absorptionskälteanlage, werden dynamische Simulationsmodelle in der Modellierungssprache Modelica entwickelt und mit Messdaten validiert.

Im Rahmen dieses Konferenzbeitrags werden Komponentenmodelle für die NH3/H2O-Absorptionskälteanlage und Simulationsrechnungen bei veränderlichen Randbedingungen präsentiert, sowie ein Vergleich mit Messdaten diskutiert.


Peer Reviewed Scientific Journals | 2020

Effects of Pyrolysis Conditions and Feedstocks on the Properties and Gasification Reactivity of Charcoal from Woodchips

Phounglamcheik A, Wang L, Romar H, Kienzl N, Broström M, Ramser K, Skreiberg Ø, Umeki K. Effects of Pyrolysis Conditions and Feedstocks on the Properties and Gasification Reactivity of Charcoal from Woodchips. Energy and Fuels. 2020;34(7):8353-8365.

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Pyrolysis conditions in charcoal production affect yields, properties, and further use of charcoal. Reactivity is a critical property when using charcoal as an alternative to fossil coal and coke, as fuel or reductant, in different industrial processes. This work aimed to obtain a holistic understanding of the effects of pyrolysis conditions on the reactivity of charcoal. Notably, this study focuses on the complex effects that appear when producing charcoal from large biomass particles in comparison with the literature on pulverized biomass. Charcoals were produced from woodchips under a variety of pyrolysis conditions (heating rate, temperature, reaction gas, type of biomass, and bio-oil embedding). Gasification reactivity of produced charcoal was determined through thermogravimetric analysis under isothermal conditions of 850 °C and 20% of CO2. The charcoals were characterized for the elemental composition, specific surface area, pore volume and distribution, and carbon structure. The analysis results were used to elucidate the relationship between the pyrolysis conditions and the reactivity. Heating rate and temperature were the most influential pyrolysis parameters affecting charcoal reactivity, followed by the reaction gas and bio-oil embedding. The effects of these pyrolysis conditions on charcoal reactivity could primarily be explained by the difference in the meso- and macropore volume and the size and structural order of aromatic clusters. The lower reactivity of slow pyrolysis charcoals also coincided with their lower catalytic inorganic content. The reactivity difference between spruce and birch charcoals appears to be mainly caused by the difference in catalytically active inorganic elements. Contrary to pyrolysis of pulverized biomass, a low heating rate produced a higher specific surface area compared with a high heating rate. Furthermore, the porous structure and the reactivity of charcoal produced from woodchips were influenced when the secondary char formation was promoted, which cannot be observed in pyrolysis of pulverized biomass.


Conference contributions | 2020

Erneuerbare in Österreich - Die Marktdiffusion im Lichte der Klima- und Energieziele

Biermayr P, Leonhartsberger K, Dißauer C; Eberl M, Enigl M, Fechner H, Lukas Fischer L, Fürnsinn B, Moidl S, Schmidl C, Strasser C, Weiss W, Wonisch P, Wopienka E. Erneuerbare in Österreich - Die Marktdiffusion im Lichte der Klima- und Energieziele. EnInnov 2020, 16. Symposium Energieinnovation (oral presentation). 2020.

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Conference contributions | 2020

Evaluation of gas cleaning processes for the coupling of biomass gasification with Solid Oxide Fuel Cells (SOFC)

Martini S, Lagler J, Kienzl N, Tsiotsias T, Rettschitzegger S. Evaluation of gas cleaning processes for the coupling of biomass gasification with Solid Oxide Fuel Cells (SOFC). 6th Central European Biomass Conference (oral presentation). 2020.

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Peer Reviewed Scientific Journals | 2020

Evaluation of heat transfer models at various fluidization velocities for biomass pyrolysis conducted in a bubbling fluidized bed

von Berg L, Soria-Verdugo A, Hochenauer C, Scharler R, Anca-Couce A. Evaluation of heat transfer models at various fluidization velocities for biomass pyrolysis conducted in a bubbling fluidized bed. International Journal of Heat and Mass Transfer. 2020;160:120175

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Four different models for heat transfer to the particles immersed in a fluidized bed were evaluated and implemented into an existing single particle model. Pyrolysis experiments have been conducted using a fluidized bed installed on a balance at different temperatures and fluidization velocities using softwood pellets. Using a heat transfer model applicable for fluidized beds, the single particle model was able to predict the experimental results of mass loss obtained in this study as well as experimental data from literature with a reasonable accuracy. A good agreement between experimental and modeling results was found for different reactor temperatures and configurations as well as different biomass types, particle sizes – in the typical range of pellets - and fluidization velocities when they were higher than . However, significant deviations were found for fluidization velocities close to minimum fluidization. Heat transfer models which consider the influence of fluidization velocity show a better agreement in this case although differences are still present.


Conference Papers | 2020

Evaluation of the Transient Behaviour of a Fixed-Bed Biomass Gasifier for Demand-Oriented Electricity Production

Hollenstein C, Zemann C, Antolini D, Patuzzi F, Martini S, Baratieri M, Gölles M. Horn M. Evaluation of the Transient Behaviour of a Fixed-Bed Biomass Gasifier for Demand-Oriented Electricity Production. 28th European Biomass Conference & Exhibition. 6-9 July 2020.

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The majority of renewable energy technologies are volatile in nature. External factors such as weather conditions lead to fluctuations in their produced electricity and heat. This results in a demand either not being covered or dissatisfied since too much electricity and heat is produced in the energy system. Although energy storages can counteract these fluctuations, renewable energy technologies that are capable of producing energy on demand are needed as well. As such, technologies based on the thermochemical conversion of biomass are especially relevant as they are considered to be CO2-neutral. Although most existing implementations are based on combustion of biomass, fixed-bed biomass gasification is of growing relevance due to higher overall efficiencies and low pollutant emissions. Currently, fixed-bed biomass gasifiers are usually operated at steady-state operation to produce the maximum amount of energy possible. This contribution investigates, whether they can be used as a technology for demand-oriented electricity and heat production


Other publication | 2020

EVEmBi – Bestimmung von Methanemissionen aus Biogasanlagen und Reduktionsstrategien

Meixner K. EVEmBi – Bestimmung von Methanemissionen aus Biogasanlagen und Reduktionsstrategien. CEBC 2020

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Conference contributions | 2020

Experimental investigation of biomass based reducing agents for blast furnace ironmaking

Kienzl N, Strasser C, Deutsch R. Experimental investigation of biomass based reducing agents for blast furnace ironmaking. 6th Central European Biomass Conference (oral presentation). 2020.

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Conference Papers | 2020

Experimentally verified dynamic simulation model of a NH3/H2O-absorption refrigeration system

Wernhart M, Rieberer R, Zlabinger S, Unterberger V, Gölles M. Experimentally verified dynamic simulation model of a NH3/H2O-absorption refrigeration system. in Japan Society of Refrigerating and Air Conditioning Engineers, Hrsg., 14th IIR Gustav-Lorentzen Conference on Natural Fluids, GL 2020 - Proceedings. International Institute of Refrigeration. 2020. S. 103-109. (Refrigeration Science and Technology). https://doi.org/10.18462/iir.gl.2020.1145

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The operation characteristics of thermally driven absorption refrigeration systems (ARS) are strongly dependent on their hydraulic integration. Therefore, varying operating conditions of the hydraulic supply have a great influence on the behaviour of ARS and lead to dynamic operation, which can affect the efficiency and is largely unexplored so far. To enable a simple investigation of ARS integration considering their dynamic behaviour and to develop modern, efficiency-enhancing control strategies, dynamic simulation models of ARS are developed in Modelica Code.

In this paper, a dynamic simulation model of an ARS with the working pair ammonia/water (NH3/H2O) is presented. The parameterization and the physical correlations of selected components of the simulation model are described. Afterwards, the simulation model is verified by comparing simulation results with measurement data of the NH3/H2O-ARS. Finally, the capabilities of the simulation model are demonstrated by performing a simulation-based analysis of the temperature glide of the refrigerant in the evaporator.


Peer Reviewed Scientific Journals | 2020

Fate of Phosphorus in Fluidized Bed Cocombustion of Chicken Litter with Wheat Straw and Bark Residues

Häggström G, Fürsatz K, Kuba M, Skoglund N, Öhman M. Fate of Phosphorus in Fluidized Bed Cocombustion of Chicken Litter with Wheat Straw and Bark Residues. Energy and Fuels. 2020.34:1822-1829

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This study aims to determine the fate of P during fluidized bed co-combustion of chicken litter (CL) with K-rich fuels [e.g., wheat straw (WS)] and Ca-rich fuels (bark). The effect of fuel blending on phosphate speciation in ash was investigated. This was performed by chemical characterization of ash fractions to determine which phosphate compounds had formed and identify plausible ash transformation reactions for P. The ash fractions were produced in combustion experiments using CL and fuel blends with 30% CL and WS or bark (B) at 790–810 °C in a 5 kW laboratory-scale bubbling fluidized bed. Potassium feldspar was used as the bed material. Bed ash particles, cyclone ash, and particulate matter (PM) were collected and subjected to chemical analysis with scanning electron microscopy–energy-dispersive X-ray spectrometry (SEM–EDS) and X-ray diffraction. P was detected in coarse ash fractions only, that is, bed ash, cyclone ash, and coarse PM fraction (>1 μm); no P could be detected in the fine PM fraction (<1 μm). SEM–EDS analysis showed that P was mainly present in K–Ca–P-rich areas for pure CL as well as in the ashes from the fuel blends of CL with WS or B. In the WS blend, P was found together with Si in these areas. The crystalline compound containing P was hydroxyapatite in all cases as well as whitlockite in the cases of pure CL and WS blend, of which the latter compound has been previously identified as a promising plant nutrient. The ash fractions from CL and bark blend only contained P in hydroxyapatite. Co-combustion of CL together with WS appears to be promising for P recovery, and ashes with this composition could be further studied in plant growth experiments


Conference contributions | 2020

GrateAdvance - Advanced adjustable grate solutions for future fuel flexible biomass combustion technologies

Barroso G, Essl M, Feldmeier S, Mehrabian R, Nussbaumer T, Öhman M, Reiterer T, Schwarz M, Shiehnejad-Hesar A, Wopienka E. GrateAdvance - Advanced adjustable grate solutions for future fuel flexible biomass combustion technologies. 6th Central European Biomass Conference, 2020, Graz.

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Conference contributions | 2020

GrateAdvance – Advanced adjustable grate solutions for future fuel flexible biomass combustion technologies

Barroso G, Essl M, Feldmeier S, Mehrabian R, Nussbaumer T, Öhman M, Reiterer T, Schwarz M, Shiehnejad-Hesar A, Wopienka E. GrateAdvance – Advanced adjustable grate solutions for future fuel flexible biomass combustion technologies. 6th Central European Biomass Conference - IEA-Workshop: TASK 32 (oral presentation). 2020.

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Conference contributions | 2020

How to create value chains from different feedstocks

Enigl M, How to create value chains from different feedstocks. 6th Central Eurpean Biomass Conference, 22-254 January 2020, Graz.

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Peer Reviewed Scientific Journals | 2020

Impact of residual fuel ash layers on the catalytic activation of K-feldspar regarding the water–gas shift reaction

Fürsatz K, Kuba M, Janisch D, Aziaba K, Hammerl C, Chlebda D, Łojewska J, Hofbauer H. Impact of residual fuel ash layers on the catalytic activation of K-feldspar regarding the water–gas shift reaction. Biomass Conversion and Biorefinery. 2020

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Interaction of biomass ash and bed materials in thermochemical conversion in fluidized beds leads to changes of the bed particle surface due to ash layer formation. Ash components present on the bed particle surface strongly depend on the ash composition of the fuel. Thus, the residual biomass used has a strong influence on the surface changes on bed particles in fluidized bed conversion processes and, therefore, on the catalytic performance of the bed material layers. Ash layer formation is associated with an increase in the catalytic activity of the bed particles in gasification and plays a key role in the operability of different biomass fuels. The catalytic activation over time was observed for K-feldspar used as the bed material with bark, chicken manure, and a mixture of bark and chicken manure as fuels. The changes on the bed material surfaces were further characterized by SEM/EDS and BET analyses. Raman, XPS, and XRD analyses were used to characterize the crystal phases on the bed material surface. An increase in surface area over time was observed for K-feldspar during the interaction with biomass ash. Additionally, a more inhomogeneous surface composition for fuels containing chicken manure in comparison to pure bark was observed. This was due to the active participation of phosphorus from the fuel ash in the ash transformation reactions leading to their presence on the particle surface. A decreased catalytic activity was observed for the same BET surface area compared to bark combustion, caused by the different fuel ash composition of chicken manure.


Peer Reviewed Scientific Journals | 2020

Increased efficiency of dual fluidized bed plants via a novel control strategy

Nigitz T, Gölles M, Aichernig C, Schneider S, Hofbauer H, Horn M. Increased efficiency of dual fluidized bed plants via a novel control strategy. Biomass & Bioenergy. 2020 Okt;141. 105688. https://doi.org/10.1016/j.biombioe.2020.105688

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Industrial plants using DFB biomass gasification are on the verge of profitability. These plants should be operated more economically in order to support the industrial applications for renewable technologies of this kind. Since some parts of such plants are typically difficult to control, a state-of-the-art control strategy is analyzed here in the context of its potential for increased economic efficiency. The DFB gasification plant “HGA Senden” in Ulm, Germany is considered on an exemplary basis here. A process analysis reveals a high potential in the synchronization of product gas generation and utilization. At the present time a relevant surplus of product gas is burned in an auxiliary boiler for synchronization purposes and regular manual adjustments at the fuel feed are necessary by the plant operators. For this synchronization a novel control strategy is developed that actuates the auxiliary boiler and the fuel feed simultaneously. The novel control strategy was experimentally validated for a period of over one month. Due to this long-term evaluation the fuel consumption was reduced by 5% and the manual adjustments of the fuel feed that were necessary on average every 30min were eliminated. As a result DFB gasification plants can be operated more economically by applying the novel control strategy for synchronization of product gas generation and utilization.


Conference contributions | 2020

Individiual heat management in the living room

Schwabl M. Individiual heat management in the living room. 6th Central European Biomass Conference (oral presentation. 2020.

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Conference contributions | 2020

Individual heat management in the living room

Schwabl M. Individual heat management in the living room. 6th Central European Biomass Conference, 22-24 January 2020, Graz.

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Conference contributions | 2020

Influence of ash forming elements from biogenous residues on fluidized bed conversion processes

Fürsatz K, Influence of ash forming elements from biogenous residues on fluidized bed conversion processes. 6th Central Eurpean Biomass Conference, 22-24 January 2020, Graz.

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Peer Reviewed Scientific Journals | 2020

Influence of bed materials on the performance of the Nong Bua dual fluidized bed gasification power plant in Thailand

Siriwongrungson V, Hongrapipat J, Kuba M, Rauch R, Pang S, Thaveesri J, Messner M, Hofbauer H. Influence of bed materials on the performance of the Nong Bua dual fluidized bed gasification power plant in Thailand. Biomass Conversion and Biorefinery. 2020;

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Bed materials and their catalytic activity are two main parameters that affect the performance of the dual fluidized bed (DFB) gasification system in terms of product gas composition and tar levels. Two sources of bed materials were used for the operation of a commercial DFB gasification system in Thailand, using woodchips as a biomass feedstock. One source of the bed materials was the calcined olivine which had been used in the Gussing Plant, Austria, and the other activated bed material was a mixture of fresh Chinese olivine and used Austrian olivine with additives of biomass ash, calcium hydroxide and dolomite. These bed materials were collected and analysed for morphological and chemical composition using a scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray fluorescence spectroscopy (XRF). The product gas was cleaned in a scrubber to remove tars, from which the samples were collected for gravimetric tar analysis. Its composition data was automatically recorded at the operation site before it entered the gas engine. From the SEM, EDS and XRF analyses, calcium-rich layers around the bed materials were observed on the activated bed material. The inner layers of bed materials collected were homogeneous. Biomass ash, which was generally added to the bed materials, had significant calcium and potassium content. These calcium-rich layers of the bed materials, from the calcium hydroxide, biomass ash and dolomite, influenced system performance, which was determined by observing lower tar concentration and higher hydrogen concentration in the product gas.


Conference contributions | 2020

Integrating steam gasification into established infrastructure in the pulp and paper industry

Karl T, Integrating steam gasification into established infrastructure in the pulp and paper industry. 6th Central European Biomass Conference, 22-24 January 2020, Graz.

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Conference contributions | 2020

Integration von Biogas in Bioprozesse - Nährstoffrückführung und Energiegewinnung

Drosg B. Integration von Biogas in Bioprozesse - Nährstoffrückführung und Energiegewinnung. 6th Central European Biomass Conference (oral presentation). 2020.

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Peer Reviewed Scientific Journals | 2020

Investigation of solid oxide fuel cell operation with synthetic biomass gasification product gases as a basis for enhancing its performance

Pongratz G, Subotić V, Schroettner H, Stoeckl B, Hochenauer C, Anca-Couce A, Scharler R. Investigation of solid oxide fuel cell operation with synthetic biomass gasification product gases as a basis for enhancing its performance. Biomass Conversion and Biorefinery.2020.

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Solid oxide fuel cells represent a promising technology to increase the electrical efficiency of biomass-based combined-heat-power systems in comparison to state-of-the-art gas engines, additionally providing high temperature heat. To identify favorable fuel gas compositions for an efficient coupling with gasifiers at low degradation risk is of major importance to ensure stability, reliability, and durability of the systems used, thus increasing attractiveness of electricity production from biomass. Therefore, this study presents a comprehensive analysis on the influence of main gas components from biomass gasification on the performance and efficiency of a cell relevant for real application. An industrial-size electrolyte supported single cell with nickel/gadolinium-doped ceria anode was selected showing high potential for gasifier-solid oxide fuel cell systems. Beneficial gas component ratios enhancing the power output and electric efficiency are proposed based on the experimental study performed. Furthermore, the degradation stability of a SOFC fueled with a synthetic product gas representing steam gasification of woody biomass was investigated. After 500 h of operation under load at a steam-to-carbon ratio of 2.25 in the fuel gas, no performance or anode degradation could be detected.


Technical Reports | 2020

Investigation of the formation of coherent ash residues during fluidized bed gasification of wheat straw lignin

Priscak J, Fürsatz K, Kuba M, Skoglund N, Benedikt F, Hofbauer H. Investigation of the formation of coherent ash residues during fluidized bed gasification of wheat straw lignin. Energies. 2020;13(15):3935:

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Thermal conversion of ash-rich fuels in fluidized bed systems is often associated with extensive operation problems caused by the high amount of reactive inorganics. This paper investigates the behavior of wheat straw lignin—a potential renewable fuel for dual fluidized bed gasification. The formation of coherent ash residues and its impact on the operation performance has been investigated and was supported by thermochemical equilibrium calculations in FactSage 7.3. The formation of those ash residues, and their subsequent accumulation on the surface of the fluidized bed, causes temperature and pressure fluctuations, which negatively influence the steady-state operation of the fluidized bed process. This paper presents a detailed characterization of the coherent ash residues, which consists mostly of silica and partially molten alkali silicates. Furthermore, the paper gives insights into the formation of these ash residues, dependent on the fuel pretreatment (pelletizing) of the wheat straw lignin, which increases their stability compared to the utilization of non-pelletized fuel.


Conference contributions | 2020

Lessons Learned from Alternative Fuels Experience

Sonnleitner A, Bacovsky D. Lessons Learned from Alternative Fuels Experience. 6th Central European Biomass Conference, 22-24 January 2020, Graz

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Decarbonising the transport sector is one of the key goals of national and international climate change mitigation policies. Rapid and effective market introduction of alternative fuels and vehicles is needed to reduce greenhouse gas emissions from the existing vehicle fleet as soon as possible and as extensively as possible.

However, experience with various attempts to introduce alternative fuels and vehicles to the market has shown that this is not always successful. Several participants in the Advanced Motor Fuels Technology Collaboration Program (AMF TCP) have therefore proposed an annex on lessons learned from market launch attempts.

The circumstances of the introduction of advanced motor fuels and the factors influencing their commercialization (resource, transport infrastructure, economic situation, etc.) in each country are different, and it is difficult to universally evaluate an advanced motor fuels policy.

For this reason, this annex clarifies the background and objective of the central government and local governments’ introduction policy and specific measures on advanced motor fuels in the past, and summarizes the effectiveness, successes, and lessons learned regarding the promotion of advanced motor fuels in each individual case of introduction and commercialization.

The participating countries Austria, China, Finland, Japan, Sweden and the USA conduct analyses of their own case studies on past market introductions taking into account specific framework conditions for each country:

Austria: low blend biofuels, CNG-driven cars, prevented introduction of E10

China: Ethanol

Finland: E10, E85, drop-in components for diesel, biogas

Japan: FAME, natural gas

Sweden: reduction obligation, high blend biofuels and biogas, E85

USA: low and high level blends of ethanol, methanol and FFVs, natural gas

The sum of the case studies is analysed and key drivers of successes and key barriers of failures are identified. Preliminary results from this work will be discussed in an expert workshop in 2020, and then the final lessons learned and recommendations will be derived. Policy briefs including key messages, best practices, lessons learned and avoided mistakes related to advanced motor fuels covering both fuels and related vehicle technologies will be developed and provided as recommendations for political decision makers.


Conference Papers | 2020

Long-term validation of a new modular approach for CO-lambda-optimization

Zemann C, Hammer F, Gölles M, Horn M. Long-term validation of a new modular approach for CO-lambda-optimization. 28th European Biomass Conference & Exhibition. 6-9 July 2020.

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Long Term Validation of a New Modular Approach for CO-Lambda-Optimization

The optimization of existing biomass boilers in terms of efficiency and pollutant emissions is essential for their continued economic and ecological viability in future energy systems. These improvements are typically achieved by constructive changes which are expensive and can require prolonged downtimes. A well-known method for optimizing biomass boilers in terms of efficiency and pollutant emissions without constructive changes is the so-called CO-lambda-optimization. While multiple approaches for CO-lambda-optimization have been presented in literature, they are still rarely used in real biomass boilers. This is partly due to the fact that these approaches do not meet the requirements associated with their long-term operation in real biomass boilers. This contribution presents a new and modular approach for the CO-lambda-optimization which is specifically designed to meet these requirements. Particular emphasis in this contribution is laid on the long-term validation of the presented approach for CO-lambda-optimization at a medium-scale fixed-bed biomass boiler.