object(App\Model\Entity\Projectscontent) { 'id' => (int) 44, 'project_id' => (int) 411, 'longtitle_de' => 'Potential der Thermischen-Biomasse-Dampf-Vergasung zur Erzeugung von Wasserstoff, synthetischem Erdgas, Strom und Fernwärme', 'longtitle_en' => 'Potential of Thermal Steam Biomass Gasification for the production of Hydrogen, SNG, Electricity and District heat', 'content_de' => '<p>Die Thermische Dampfvergasung von Biomasse bietet großes Potential hinsichtlich der Erzeugung von verschiedenen Produkten aus einem einzigen Einsatzstoff. The Zweibett-Wirbelschicht-Dampfvergasung von Biomasse erzeugt ein N<sub>2</sub> freies Produktgas mit hohem Heizwert und einer volumetrischen Gaszusammensetzung von ca. 40 % H<sub>2</sub>, 25 % CO, 23 % CO<sub>2</sub>, 10 % CH<sub>4</sub> und etwa 2 % höheren Kohlenwasserstoffen. Dieses Produktgas ist Ausgangspunkt für verschiedene Polygeneration Konzepte, die auf die Erzeugung von H<sub>2</sub>, synthetischem Erdgas, Strom, und Wärme abzielen. Dabei sollen nur Verfahren eingesetzt werden, die dem Stand der Technik entsprechen, z.B. Wassergas-Shift, Druckwechseladsorption oder Methanierung. Zusätzlich wäre es möglich CO und CO<sub>2</sub> aus dem Produktgas abzutrennen, um diese Stoffe als Rohrstoff in der chemischen Industrie einzusetzen.</p> <p>H<sub>2</sub> ist als Einsatzstoff für die chemische Industrie sowie als zukünftiger Kohlenstofffreier Energieträger im Gespräch. Synthetisches Erdgas kann in bereits vorhandener Infrastruktur einfach gespeichert und verteilt werden. Strom kann durch Verbrennung des Produktgases in Gasmotoren erzeugt werden. Zusätzlich kann auch Wärme, die während des Vergasungsprozesses anfällt in einem ORC Prozess verstromt werden. Fernwärme kann durch Verbrennung des Produktgases sowie aus Überschusswärme des Vergasungsprozesses bereitgestellt werden.</p> <p>Dieses Projekt zeigt, dass Biomasse für mehr als nur zur Erzeugung von Strom und Wärme eingesetzt werden kann. Vielmehr ist die Biomasse ein Einsatzstoff für die Erzeugung von Energieträgern bzw. von Rohstoffen für die chemische Industrie.</p> ', 'content_en' => '<p>Steam gasification of biomass offers a great potential for polygeneration concepts, which aim at the generation of various products from a single feedstock. The dual fluidized bed biomass steam gasification of biomass generates a N<sub>2</sub> free product with high calorific value and a volumetric gas composition of about 40 % H<sub>2</sub>, 25 % CO, 23 % CO<sub>2</sub>, 10 % CH<sub>4</sub>, and about 2 % of higher hydrocarbons. This product gas is the feedstock for polygeneration concepts aiming at the generation of H<sub>2</sub>, CH<sub>4</sub> (synthetic natural gas), electricity, and heat based on state of the art unit operations, like water gas shift, pressure swing adsorption, or methanation. Moreover, there is also the possibility to separate CO and CO<sub>2</sub> from the product gas in order to use them as basis chemical for industry.</p> <p>H<sub>2</sub> is of interest as feed stock for industry and as possible carbon free energy carrier in the future. CH<sub>4</sub> or synthetic natural gas can easily be stored and distributed in existing natural gas grids. Electricity can be generated by combustion of product gas in a gas engine or by using excess heat of the gasification process in an Organic Rankine Cycle. Heat can be generated through combustion of product gas or by using excess heat of the gasification process.</p> <p>This project shows that biomass can be used for more than just electricity and heat generation. Moreover, it can serve as feedstock for the generation of energy carriers or for important basic chemicals for industry.</p> ', 'image_1' => '', 'image_1_caption_de' => '', 'image_1_caption_en' => '', 'image_1_credits_de' => '', 'image_1_credits_en' => '', 'image_2' => '', 'image_2_caption_de' => '', 'image_2_caption_en' => '', 'image_2_credits_de' => '', 'image_2_credits_en' => '', 'image_3' => '', 'image_3_caption_de' => '', 'image_3_caption_en' => '', 'image_3_credits_de' => '', 'image_3_credits_en' => '', 'logos' => '<p>Air Liquide</p> <p>Güssing Renewable Energy</p> <p>Technische Universiät Wien</p> ', 'finanzierung' => '<p>FFG, COMET</p> ', 'active' => true, 'created' => null, 'modified' => null, 'projektvolumen' => '', 'project' => object(App\Model\Entity\Project) { 'Nummer' => (int) 411, 'Projektnummer' => 'C20005016', 'Kurzbezeichnung' => 'POLYGENERATION', 'Kurzbezeichnung_en' => '', 'Oeffentlich' => '1', 'Projektname' => 'Polygeneration', 'Projektname_en' => '', 'Projektleitung' => (int) 1078, 'Start' => object(Cake\I18n\FrozenDate) { 'time' => '2015-04-01 00:00:00.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'Ende' => object(Cake\I18n\FrozenDate) { 'time' => '2019-03-31 00:00:00.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'publications' => [ (int) 0 => object(App\Model\Entity\Publication) { 'id' => (int) 795, 'titel' => 'Performance of a water gas shift unit processing tar-rich product gas from a commercial dual fluidized bed biomass steam gasification plant which operates at partial load', 'subtitel' => '', 'autor' => 'Kraussler M, Binder M, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2017, 'datum_publikation' => '', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 9, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Binder M, Hofbauer H. Performance of a water gas shift unit processing tar-rich product gas from a commercial dual fluidized bed biomass steam gasification plant which operates at partial load. International Journal of Oil, Gas and Coal Technology. 2017;14(1-2): 32-48.', 'abstract' => '<p>In this paper, the performance of a water gas shift unit processing product gas from a commercial dual fluidised bed biomass steam gasification plant is studied. The experiments were carried out during a partial load operation of the gasification plant. In order to investigate a water gas shift process, a water gas shift unit, located at the site of the gasification plant in Oberwart, Austria, was used. The water gas shift unit consisted of three reactors in series filled with a commercial Fe'Cr-based catalyst and was operated with tar-rich product gas. No performance decrease of the water gas shift unit was observed during the partial load operation of the gasification plant. Furthermore, a CO conversion of 92% and a GCMS tar reduction of about 30% were reached. In addition, it was found that partial load operation of the gasification plant did not negatively affect the performance of the water gas shift unit.</p> ', 'pdf_file' => '', 'hyperlink' => 'https://doi.org/10.1504/IJOGCT.2017.081098', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-07 08:55:47.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 10:07:44.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 416, 'project_id' => (int) 411, 'publication_id' => (int) 795, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 10:07:44.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 10:07:44.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 1 => object(App\Model\Entity\Publication) { 'id' => (int) 797, 'titel' => 'Behavior of GCMS tar components in a water gas shift unit operated with tar-rich product gas from an industrial scale dual fluidized bed biomass steam gasification plant', 'subtitel' => '', 'autor' => 'Kraussler M, Binder M, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2017, 'datum_publikation' => '1 March 2017', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 9, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Binder M, Hofbauer H. Behavior of GCMS tar components in a water gas shift unit operated with tar-rich product gas from an industrial scale dual fluidized bed biomass steam gasification plant. Biomass Conversion and Biorefinery. 1 March 2017;7(1): 69-79.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => 'https://link.springer.com/article/10.1007/s13399-016-0205-y', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-07 09:01:07.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 11:54:15.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 417, 'project_id' => (int) 411, 'publication_id' => (int) 797, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 11:54:15.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 11:54:15.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 2 => object(App\Model\Entity\Publication) { 'id' => (int) 807, 'titel' => 'Techno-economic assessment of hydrogen production based on dual fluidized bed biomass steam gasification, biogas steam reforming, and alkaline water electrolysis processes', 'subtitel' => '', 'autor' => 'Yao J, Kraussler M, Benedikt F, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2017, 'datum_publikation' => '1 August 2017', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 9, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Yao J, Kraussler M, Benedikt F, Hofbauer H. Techno-economic assessment of hydrogen production based on dual fluidized bed biomass steam gasification, biogas steam reforming, and alkaline water electrolysis processes. Energy Conversion and Management. 1 August 2017;145: 278-292.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => 'http://www.sciencedirect.com/science/article/pii/S0196890417304065', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-07 09:25:03.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:04:22.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 419, 'project_id' => (int) 411, 'publication_id' => (int) 807, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:04:23.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:04:23.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 3 => object(App\Model\Entity\Publication) { 'id' => (int) 808, 'titel' => 'An experimental approach aiming the production of a gas mixture composed of hydrogen and methane from biomass as natural gas substitute in industrial applications', 'subtitel' => '', 'autor' => 'Kraussler M, Schindler P, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2017, 'datum_publikation' => 'August 2017', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 9, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Schindler P, Hofbauer H. An experimental approach aiming the production of a gas mixture composed of hydrogen and methane from biomass as natural gas substitute in industrial applications. Bioresource Technology. August 2017;237: 39-46.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => 'http://www.sciencedirect.com/science/article/pii/S0960852417303103', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-07 09:26:39.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:05:50.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 420, 'project_id' => (int) 411, 'publication_id' => (int) 808, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:05:50.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:05:50.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 4 => object(App\Model\Entity\Publication) { 'id' => (int) 878, 'titel' => 'Wasserstoff aus Biomasse - Stand der Technik und Perspektiven', 'subtitel' => '', 'autor' => 'Hofbauer H, Bosch K, Kraussler M', 'herausgeber' => '', 'jahr' => (int) 2017, 'datum_publikation' => 'January 2017', 'publications_type_id' => (int) 2, 'publications_category_id' => (int) 1, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Hofbauer H, Bosch K, Kraussler M. Wasserstoff aus Biomasse - Stand der Technik und Perspektiven. 5th Central European Biomass Conference (oral presentation). January 2017, Graz, Austria.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => '', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-11 11:00:54.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:24:07.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 422, 'project_id' => (int) 411, 'publication_id' => (int) 878, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:24:08.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:24:08.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 5 => object(App\Model\Entity\Publication) { 'id' => (int) 880, 'titel' => 'HCNG or hythane production from biomass steam gasification', 'subtitel' => '', 'autor' => 'Kraussler M, Priscak J, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2017, 'datum_publikation' => 'January 2017', 'publications_type_id' => (int) 2, 'publications_category_id' => (int) 1, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Priscak J, Hofbauer H. HCNG or hythane production from biomass steam gasification. 5th Central European Biomass Conference (oral presentation). January 2017, Graz, Austria.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => '', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-11 11:04:23.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:25:55.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 423, 'project_id' => (int) 411, 'publication_id' => (int) 880, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:25:55.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:25:55.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 6 => object(App\Model\Entity\Publication) { 'id' => (int) 907, 'titel' => 'Polygeneration of hydrogen and a gas mixture composed of H2 and CH4 via sorption enhanced reforming of biomass', 'subtitel' => '', 'autor' => 'Kraussler M, Priscak J, Benedikt F, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2017, 'datum_publikation' => 'June 2017', 'publications_type_id' => (int) 2, 'publications_category_id' => (int) 1, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Priscak J, Benedikt F, Hofbauer H. Polygeneration of hydrogen and a gas mixture composed of H2 and CH4 via sorption enhanced reforming of biomass. 25th European Biomass Conference & Exhibition (oral presentation). June 2017, Stockholm, Sweden. ', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => '', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-16 08:59:27.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:28:31.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 425, 'project_id' => (int) 411, 'publication_id' => (int) 907, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:28:32.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:28:32.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 7 => object(App\Model\Entity\Publication) { 'id' => (int) 771, 'titel' => '2250-h long term operation of a water gas shift pilot plant processing tar-rich product gas from an industrial scale dual fluidized bed biomass steam gasification plant', 'subtitel' => '', 'autor' => 'Kraussler M, Binder M, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2016, 'datum_publikation' => '27 April 2016', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 9, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Binder M, Hofbauer H. 2250-h long term operation of a water gas shift pilot plant processing tar-rich product gas from an industrial scale dual fluidized bed biomass steam gasification plant. International Journal of Hydrogen Energy. 27 April 2016;41(15): 6247-6258.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => 'http://www.sciencedirect.com/science/article/pii/S0360319915308910', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-04 10:07:17.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:35:36.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 429, 'project_id' => (int) 411, 'publication_id' => (int) 771, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:35:36.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:35:36.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 8 => object(App\Model\Entity\Publication) { 'id' => (int) 875, 'titel' => 'Hythane from biomass steam gasification as natural gas substitute in industrial applications', 'subtitel' => '', 'autor' => 'Kraussler M, Schindler P, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2016, 'datum_publikation' => 'October 2016', 'publications_type_id' => (int) 2, 'publications_category_id' => (int) 1, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Schindler P, Hofbauer H. Hythane from biomass steam gasification as natural gas substitute in industrial applications. Biorestec (poster). October 2016, Sitges, Spain.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => '', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-11 10:37:26.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:48:37.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 430, 'project_id' => (int) 411, 'publication_id' => (int) 875, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:48:37.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:48:37.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 9 => object(App\Model\Entity\Publication) { 'id' => (int) 815, 'titel' => 'Hydrogen production within a polygeneration concept based on dual fluidized bed biomass steam gasification', 'subtitel' => '', 'autor' => 'Kraussler M, Binder M, Schindler P, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2016, 'datum_publikation' => '24 December 2016', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 9, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Binder M, Schindler P, Hofbauer H. Hydrogen production within a polygeneration concept based on dual fluidized bed biomass steam gasification. Biomass and Bioenergy. 24 December 2016;', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => 'http://www.sciencedirect.com/science/article/pii/S0961953416303750', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-08 08:43:53.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:49:13.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 431, 'project_id' => (int) 411, 'publication_id' => (int) 815, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:49:14.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:49:14.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 10 => object(App\Model\Entity\Publication) { 'id' => (int) 849, 'titel' => 'Progress in hydrogen production from product gas generated by dual fluidized bed biomass steam gasification', 'subtitel' => '', 'autor' => 'Kraussler M, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2016, 'datum_publikation' => 'June 2016', 'publications_type_id' => (int) 2, 'publications_category_id' => (int) 1, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Hofbauer H. Progress in hydrogen production from product gas generated by dual fluidized bed biomass steam gasification. 24th European Biomass Conference & Exhibition (oral presentation). June 2016, Amsterdam, Netherlands. ', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => '', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-10 10:55:38.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:55:31.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 432, 'project_id' => (int) 411, 'publication_id' => (int) 849, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:55:32.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 12:55:32.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 11 => object(App\Model\Entity\Publication) { 'id' => (int) 754, 'titel' => 'Performance of a water gas shift pilot plant processing product gas from an industrial scale biomass steam gasification plant', 'subtitel' => '', 'autor' => 'Kraussler M, Binder M, Fail S, Bosch K, Hackel M, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2015, 'datum_publikation' => '4 August 2015', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 9, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Binder M, Fail S, Bosch K, Hackel M, Hofbauer H. Performance of a water gas shift pilot plant processing product gas from an industrial scale biomass steam gasification plant. Biomass and Bioenergy. 4 August 2015;89:50-57.', 'abstract' => '<p>In this paper, the performance of a commercial Fe/Cr based catalyst for the water gas shift reaction was investigated. The catalyst was used in a water gas shift pilot plant which processed real product gas from a commercial biomass steam gasification plant with two different qualities: extracted before and extracted after scrubbing with a rapeseed methyl ester gas scrubber. The performance of the WGS pilot plant regarding these two different gas qualities was investigated. For this reason, extensive chemical analyses were carried out. CO, CO<sub>2</sub>, CH<sub>4</sub>, N<sub>2</sub>, O<sub>2</sub>, C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>4</sub>, and C<sub>2</sub>H<sub>2</sub> and H<sub>2</sub>S, COS, and C<sub>4</sub>H<sub>4</sub> S were measured. In addition, GCMS tar and NH<sub>3</sub> analyses were performed. Furthermore, the catalyst's activity was observed by measuring the temperature profiles along the reactors of the water gas shift pilot plant. During the 200 h of operation with both product gas qualities, no catalyst deactivation could be observed. A CO conversion up to 93% as well as a GCMS tar reduction (about 28%) along the water gas shift pilot plant was obtained. Furthermore, a specific H<sub>2</sub> production of 63 g H<sub>2</sub> per kg biomass (dry and ash free) was reached with both product gas qualities. No significant performance difference could be observed.</p> ', 'pdf_file' => '', 'hyperlink' => 'https://www.sciencedirect.com/science/article/pii/S0961953415301720', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-03 10:52:27.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 13:02:12.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 435, 'project_id' => (int) 411, 'publication_id' => (int) 754, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 13:02:13.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 13:02:13.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 12 => object(App\Model\Entity\Publication) { 'id' => (int) 826, 'titel' => 'Validation of a Kinetic Model for the Catalyzed Water Gas Shift Reaction Applying a Fe/Cr Catalyst Processing Wood Gas from Biomass Steam Gasification', 'subtitel' => '', 'autor' => 'Kraussler M, Fail S, Plaza Quevedo A, Cortes Guerro JA, Rauch R, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2015, 'datum_publikation' => 'June 2015', 'publications_type_id' => (int) 2, 'publications_category_id' => (int) 1, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Fail S, Plaza Quevedo A, Cortes Guerro JA, Rauch R, Hofbauer H. Validation of a Kinetic Model for the Catalyzed Water Gas Shift Reaction Applying a Fe/Cr Catalyst Processing Wood Gas from Biomass Steam Gasification. 23rd European Biomass Conference & Exhibition (Poster). June 2015, Vienna, Austria.', 'abstract' => '', 'pdf_file' => '', 'hyperlink' => '', 'downloadbar' => false, 'active' => true, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2017-08-08 09:27:23.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 13:11:32.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '_joinData' => object(App\Model\Entity\ProjectsPublication) { 'id' => (int) 436, 'project_id' => (int) 411, 'publication_id' => (int) 826, 'created' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 13:11:32.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, 'modified' => object(Cake\I18n\FrozenTime) { 'time' => '2018-02-26 13:11:32.000000+00:00', 'timezone' => 'UTC', 'fixedNowTime' => false }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'ProjectsPublications' }, '[new]' => false, '[accessible]' => [ '*' => true, 'id' => false ], '[dirty]' => [], '[original]' => [], '[virtual]' => [], '[hasErrors]' => false, '[errors]' => [], '[invalid]' => [], '[repository]' => 'Publications' }, (int) 13 => object(App\Model\Entity\Publication) { 'id' => (int) 827, 'titel' => 'Performance of a Water Gas Shift Unit Processing Product Gas from Biomass Steam Gasification', 'subtitel' => '', 'autor' => 'Kraussler M, Binder M, Fail S, Rauch R, Bosch K, Hackel M, Hofbauer H', 'herausgeber' => '', 'jahr' => (int) 2015, 'datum_publikation' => 'June 2015', 'publications_type_id' => (int) 1, 'publications_category_id' => (int) 1, 'publications_subcategory_id' => (int) 6, 'issn' => '', 'copyright' => '', 'citation' => 'Kraussler M, Binder M, Fail S, Rauch R, Bosch K, Hackel M, Hofbauer H. Performance of a Water Gas Shift Unit Processing Product Gas from Biomass Steam Gasification. 23rd European Biomass Conference & Exhibition (oral presentation). 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Potential der Thermischen-Biomasse-Dampf-Vergasung zur Erzeugung von Wasserstoff, synthetischem Erdgas, Strom und Fernwärme
Die Thermische Dampfvergasung von Biomasse bietet großes Potential hinsichtlich der Erzeugung von verschiedenen Produkten aus einem einzigen Einsatzstoff. The Zweibett-Wirbelschicht-Dampfvergasung von Biomasse erzeugt ein N2 freies Produktgas mit hohem Heizwert und einer volumetrischen Gaszusammensetzung von ca. 40 % H2, 25 % CO, 23 % CO2, 10 % CH4 und etwa 2 % höheren Kohlenwasserstoffen. Dieses Produktgas ist Ausgangspunkt für verschiedene Polygeneration Konzepte, die auf die Erzeugung von H2, synthetischem Erdgas, Strom, und Wärme abzielen. Dabei sollen nur Verfahren eingesetzt werden, die dem Stand der Technik entsprechen, z.B. Wassergas-Shift, Druckwechseladsorption oder Methanierung. Zusätzlich wäre es möglich CO und CO2 aus dem Produktgas abzutrennen, um diese Stoffe als Rohrstoff in der chemischen Industrie einzusetzen.
H2 ist als Einsatzstoff für die chemische Industrie sowie als zukünftiger Kohlenstofffreier Energieträger im Gespräch. Synthetisches Erdgas kann in bereits vorhandener Infrastruktur einfach gespeichert und verteilt werden. Strom kann durch Verbrennung des Produktgases in Gasmotoren erzeugt werden. Zusätzlich kann auch Wärme, die während des Vergasungsprozesses anfällt in einem ORC Prozess verstromt werden. Fernwärme kann durch Verbrennung des Produktgases sowie aus Überschusswärme des Vergasungsprozesses bereitgestellt werden.
Dieses Projekt zeigt, dass Biomasse für mehr als nur zur Erzeugung von Strom und Wärme eingesetzt werden kann. Vielmehr ist die Biomasse ein Einsatzstoff für die Erzeugung von Energieträgern bzw. von Rohstoffen für die chemische Industrie.
Projektlaufzeit
2015-04-01 - 2019-03-31
Finanzierung
FFG, COMET
Projektpartner
Air Liquide
Güssing Renewable Energy
Technische Universiät Wien
Ansprechperson
Matthias BINDER
matthias.binder@best-research.eu
Area Management
Matthias Kuba
matthias.kuba@best-research.eu
Gerald Weber
gerald.weber@best-research.eu
Publikationen
Wasserstoff aus Biomasse - Stand der Technik und Perspektiven
HCNG or hythane production from biomass steam gasification
Hythane from biomass steam gasification as natural gas substitute in industrial applications
Performance of a Water Gas Shift Unit Processing Product Gas from Biomass Steam Gasification